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Technical Ospho question for chemists

Discussion in 'The Hokey Ass Message Board' started by AGELE55, Dec 7, 2021.

  1. AGELE55
    Joined: Jan 4, 2018
    Posts: 672

    AGELE55
    Member

    The ospho bottle says it it converts iron oxide (rust) into iron phosphate, an inert hard substance that turns metal black.
    So if the rust is no longer rust, then why, when I sand the now black inert substance, it powders off as brown rust colored dust?
    Hmmmmm...
     
    Xman and oliver westlund like this.
  2. pitman
    Joined: May 14, 2006
    Posts: 5,148

    pitman

    Rust: the way iron comes from, or returns, to the earth. Oxide: iron & oxygen (our sometimes friend ). Phosphate does convert iron to a new compound. I've always liked the black finish. Possible the rust was the earlier top coat.
     
    38Chevy454 likes this.
  3. rusty valley
    Joined: Oct 25, 2014
    Posts: 4,351

    rusty valley
    Member

    Confusing subject. If you look at the bottle, or the website, it says you do not need to sand, or neutralize, just go ahead and paint. However, if you do a google search with "HAMB" included, you will find that most folks say the opposite. Take your pick! I sprayed it on too thick once, 3 days in a wood stove heated shop, and it never dried. Had to wipe it all down with a damp rag
     
  4. el Scotto
    Joined: Mar 3, 2004
    Posts: 4,722

    el Scotto
    Member
    from Tracy, CA

    I was using Ospho today on a surface rusty '29 truck that's been left outside. I was planning on brush painting the thing with Rustoleum just to keep it from coming back so fast since I don't plan on working on it for a while.
     
    dmar836 likes this.
  5. gsnort
    Joined: Feb 5, 2008
    Posts: 291

    gsnort
    ALLIANCE MEMBER

    I built a '47 Ford pickup for one of my grandsons fifteen years ago. I used Ospho on rust. Still no sign whatsoever of rust.
     
    klleetrucking likes this.
  6. gimpyshotrods
    Joined: May 20, 2009
    Posts: 24,551

    gimpyshotrods
    ALLIANCE MEMBER

    I just pulled a dismantled Model A cab out of a non-climate-controlled storage unit, about a mile from the salty San Francisco Bay.

    It is bare metal, coated with Ospho.

    Zero rust in one-decade.
     
    Last edited: Dec 8, 2021
  7. 38Chevy454
    Joined: Oct 19, 2001
    Posts: 6,799

    38Chevy454
    ALLIANCE MEMBER

    Ospho is phosphoric acid as the active ingredient. The iron phosphate that is on the surface is a good crystalline surface for paint adhesion. Iron phosphate by itself it is not a real good corrosion protection method. Better than bare steel, but not as good as paint for example. Iron phosphate plus paint is better than paint alone.
    Straight iron phosphate is grey color, fasteners that are phosphate coated have a drying oil put on after the phosphate which makes them dark grey or black, which acts like a sealing coat and improves corrosion protection. But paint over phosphate ( no oil) is better.
     
    pitman likes this.
  8. Lloyd's paint & glass
    Joined: Nov 16, 2019
    Posts: 10,905

    Lloyd's paint & glass
    ALLIANCE MEMBER

    Buy some POR metal prep. I like the results better. Red scotchbrite pad to knock the loose stuff off, then follow the directions on the bottle. 20190805_125706.jpg 20190805_125714.jpg
     
    210superair and Bob Lowry like this.
  9. F-ONE
    Joined: Mar 27, 2008
    Posts: 3,717

    F-ONE
    Member
    from Alabama

    Layman's Terms...
    Basically what these treatments do is "Blue-Brown-Blacken the steel much like rust blueing a gun barrel.
     
  10. AGELE55
    Joined: Jan 4, 2018
    Posts: 672

    AGELE55
    Member

    So I’m still wondering why when sanding black, it comes off as brown? Does the ospho only convert the very top surface, and the sanding cuts through to the concealed rust?
     
    Lloyd's paint & glass likes this.
  11. X38
    Joined: Feb 27, 2005
    Posts: 17,498

    X38
    Member

    I've experienced the same thing. And I think you're right, the acid hasn't soaked in/converted all the way.
     
    AGELE55 likes this.
  12. Lloyd's paint & glass
    Joined: Nov 16, 2019
    Posts: 10,905

    Lloyd's paint & glass
    ALLIANCE MEMBER

    I don't think that it ever does soak completely, I think it's more of an encapsulation.
     
    AGELE55 likes this.

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